To give a clear representation of a state function, it is often helpful to investigate the two theorems on exact differentials.
Theorem 1:
If
Provided that M and N have continuous derivatives:
Proof: The total
derivative of the function φ can be expressed in the
form:
Comparison of the above two
dφ
equations
can be expressed as:
Since the right-side of the last two equations are equal to each other, then:
Thus, the representation,
M dx + N dy can be written as the differential of φ,
i.e., dφ,
often called an exact differential.
Theorem 2
A necessary and sufficient condition for M dx + N dy to be independent of the path C joining any two points A and B is that:
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