Chemical Engineering Tutorials: Exact Differetial Theorem

Sunday, 28 March 2021

Exact Differetial Theorem

To give a clear representation of a state function, it is often helpful to investigate the two theorems on exact differentials.

Theorem 1:

If

Provided that M and N have continuous derivatives:

Proof: The total derivative of the function φ can be expressed in the form:

Comparison of the above two dφ equations can be expressed as:

Since the right-side of the last two equations are equal to each other, then:

Thus, the representation, M dx + N dy can be written as the differential of φ, i.e., dφ, often called an exact differential.

Theorem 2

A necessary and sufficient condition for M dx + N dy to be independent of the path C joining any two points A and B is that:












1 comment:

  1. I am not a chemical engineer but this blog entry is very helpful. Thanks for sharing it.

    ReplyDelete

Maxwell Relations

Background Maxwell’s equations are important for electric and magnetic fields, while Maxwell’s relations focus on thermodynamic quantities l...